Department of Chemistry mesh polymers and oligomers

Відділ створений у 1965 році. До 1998 року відділ очолювала доктор хімічних наук, професор С.І.Омельченко. В 1998 році після об’єднання з лабораторією синтезу поліуретанів відділ очолив доктор хімічних наук, професор В.В.Шевченко.

The department defended 2 doctoral and 23 master’s theses, published 4 books and about 800 articles, more than 200 patents, awarded the State Prize in Science and Technology (1981).

The main achievements of

• Scientific Approaches purposeful creation of film reticulated polyurethane considering the concentration of certain groups, the type and degree of crosslinking.
• The basic features of the formation of film reticulated polyurethane in a thin layer on the surface of various substrates in the presence of fillers.
• The methods of synthesis and received a number of hydroxyl  and silicon compounds to modify polyurethanes.
• The scientific principles of chemical modification reticulated polyurethane and silicon organic compounds.
• The mechanism and formulated the principles of radiation copolymerization oligomers in a thin layer.
• A method seeks control of the structure and properties of film-forming segmented polyurethanes by functionalization of flexible and rigid blocks.
• Approaches to regulation ion conductive properties of segmented polyurethanes.
• A new approach to regulation cohesive and adhesive characteristics of polyurethane segmented indicators and their stickiness.
• A new approach to improve the surface activity of the compounds and methods of synthesis bianchor surface-active compounds oligomeric type.

Perspective and implemented development

The following developments proposed for implementation to interested businesses and entrepreneurs in the form of mutually beneficial cooperation.

Orders for the development of polymer materials of different functions:

• Corrosion resistant epoxyerethane enamel
• and chemical resistant polyurethane enamel and epoxyerethane varnishes
• perchlorvinylurethane corrosion enamel UR-HV-72 for livestock farms, storage of fertilizers and agricultural machinery
• chemically modified resistant polyurethane enamel protection equipment plating plants chemical plants, concrete and concrete structures operating in aggressive environments
• Furniture and UV-curing coatings
• polyurethane varnish-ground of rust
• multifunctional hardener for polyurethane varnishes
• carbofunstional silicone block copolymers and polyols for the synthesis and modification of polymer coatings
• water acrylate modified enamel
• anaerobic sealing composition for impregnation of porous materials
• anaerobic composition for sealing and fixing of carving connections
• furancomntaining polymeric binders for precision casting of titanium alloys
• compositions for soldering of printed wiring connected functions preservative coatings, protective coating and flux after soldering
• Polyurethane adhesives radiation hardened permanent stickiness
• one- and two-component polyurethane adhesives of constant stickiness
• Self-adhesive decorative materials
• Adhesive grinding materials
• Adhesive Sealing materials for shipbuilding
• Self-adhesive protective films for aviation
• film adhesives of constant stickiness
• Waterproof lightweight material for inflatable membranes
• temperature-sensitive polyurethane film
• bianchor olihourethane effective surfactants for the production of polyurethane foams, films and lubricating fluids for metal, alloys, semiconductors, piezoelectric
• bactericidal surfactants with high sorption capacity

Favourites labors

1. Омельченко С.И. Сложные олигоэфиры и полимеры на их основе. – Киев: Наук.думка, 1976. – 216 с.
2. Кузнецова В.П., Ласковенко Н.Н., Запунная К.В. Кремнийорганические полиуретаны. – Киев: Наук.думка, 1981. – 220 с.
3. Омельченко С.И., Кадурина Т.И. Модифицированные полиуретаны. – Киев: Наук.думка, 1983. – 226 с.
4. Шилова О.А., Тарасюк Е.В., Шевченко В.В., Клименко Н.С., Хашковский С.В., Шилов В.В. Золь-гель синтез гибкого жаростойкого гибридного органо-неорганического покрытия с использованием полимеров различной топологии. – Вопросы химии и хим.технологии. – 2002, №3, С.254-260
5. Sidorenko A., Zhai X.W., Peleshanko S., Greco A., Shevchenko V.V., Tsukruk V.V. Hyperbranched Polyesters on Solid Surfaces. Langmuir, 2001, Vol.17, N19, p.5924-5931
6. Кадурина Т.И., Лаевская Л.И. Водоразбавляемые алкидные и уретаналалкидные пленкообразователи. Вопросы химии и хим.технологии. 2001, № 4, С.63-67 Кадурина Т.И.Лаевская Л.И.
7. Sidorenko A., Zhai X., Peleshanko S., Greco A., Shevchenko V.V., Tsukruk V.V. Adsorption of hyperbranched polymers on functionalized solid surfaces. Am. Chem. Soc.- Abstr. Pap. 2001, Vol.84, P. 414-416.
8. Polizos G., Kyritsis A., Pissis P., Shilov V.V., Shevchenko V.V. Structure and molecular mobility studies in novel polyurethane ionomers based on poly(ethylene oxide). Solid State Ionics, 2000, N136-137, Р.255-260.
9. Pissis P., Kyritsis A.,Georgiousis G., Shilov V.V., Shevchenko V.V. Structure-property relationships in proton conductors based on polyurethanes. Solid State Ionics, 2000, N136-137, Р.1139-1146.
10. Shilov V.V., Shevchenko V.V.,Pissis V.,Kyritsis A., Gomza Yu.P., Nesin S.P.,Klimenko N.S. Morfology and protonic conductivity of the polyurethanes with acid groupes in the flexible segment. Solid Stale Jonics. 1999, N120, Р.43-45.

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